Abstract: Functional polymers provide a versatile platform for engineering materials in which ionic, electronic, and mass transport can be tuned through controlled nanostructure. Yet achieving predictive performance in these systems requires understanding how phase behavior, nonequilibrium assembly, and solid-liquid interactions govern structure formation across multiple length scales.
Morphology and phase segregation fundamentally dictate charge and ion transport in applications ranging from ion-selective membranes to bioelectronic devices and biosensors. In this talk, I will discuss how nanoscale domains, interfacial structures, and nanoconfinement govern ionic partitioning and electronic percolation, and how these structural parameters can be deliberately engineered to control transport behavior and electrochemical response. By integrating materials design with quantitative nanoscale analysis enabled by cryogenic electron microscopy, we establish structure-transport relationships that support the predictive tuning of polymer blends for targeted applications.